Best film and, just to show the two don't always go hand in hand, best performance
Connery - GF - TB [or NSNA when I'm feeling old and bitter]
Lazenby - OHMSS - OHMSS
Moore - TSWLM - TMWTGG
Dalton - TLD - TLD
Brosnan - TND - TWINE
Craig - CR - CR
I think I’d agree with all of those except perhaps the performance: totally agree Sean’s at his best in TB (NSNA is a great call too; he really knows what he’s doing there) but I’d probably say Roger is at the top in Spy- he’s just effortlessly comfortable in that. Pierce is a tricky one for best performance.. I might even be tempted to go for DAD as he holds his own very well amongst all of the nonsense going on.
Craig is the only tricky one to decide on a best film/performance combo because I really can’t pick between CR and SF- I think they’re both amazing. Today I think I go for CR being his best film, but that may change tomorrow! As for best performance I might lump for SP as I like the more laid back playfulness he brings to Bond in that film.
Connery - FRWL
Lazenby - Hmmm... let me have a think about that...
Moore - OP
Dalton - LTK
Brosnan - TWINE
Craig - CR
DC: CR (haven't seen NTtD yet but I doubt it will top it).
Sean Connery: From Russia With Love
Roger Moore: For Your Eyes Only
Timothy Dalton: Licence To Kill
Pierce Brosnan: Goldeneye
Daniel Craig: Casino Royale
Sean Connery: Thunderball
George Lazenby: OHMSS of course
Sir Roger: Live and Let Die
Timothy Dalton: Licence to Kill
Sean Connery: Goldfinger
George Lazenby: OHMSS by default
Timothy Dalton: The Living Daylights
Pierce Brosnan: GoldenEye